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Structure and electrical properties of Nb-Ge-C nanocomposite coatings

机译:Nb-Ge-C纳米复合涂层的结构和电性能

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摘要

Nb-Ge-C nanocomposite thin films were deposited by dc magnetron sputtering using three elemental targets. The films consist of substoichiometric NbCx in a nanometer-thick matrix of amorphous C and Ge. Films with no Ge contain grains that are elongated in the growth direction with a (111) preferred crystallographic orientation. With the addition of ∼12 at. % Ge, the grains are more equiaxed and exhibit a more random orientation. At even higher Ge contents, the structure also becomes denser. The porous structure of the low Ge content films result in O uptake from the ambient. With higher C content in the films both the amount of amorphous C and C/Nb-ratio increases. The contact resistance was measured by four-point technique as a function of contact force between 0 and 10 N. The lowest contact resistance (1.7 mΩ) is obtained at 10 N. The resistivity varies between 470 and 1700 μΩ·cm depending on porosity and O content.
机译:Nb-Ge-C纳米复合薄膜通过直流磁控溅射使用三个元素靶沉积。该膜由亚化学计量的NbCx组成,该NbCx在无定形C和Ge的纳米厚度基质中。没有Ge的膜包含晶粒,该晶粒在生长方向上具有优选的(111)结晶取向。加上〜12 at。 %Ge,晶粒更等轴,并表现出更多的随机取向。在更高的Ge含量下,结构也变得更致密。低Ge含量的膜的多孔结构导致环境中O的吸收。随着膜中C含量的增加,无定形C的量和C / Nb比均增加。接触电阻是通过四点技术测量的,该函数是接触力在0和10 N之间的函数。最低接触电阻(1.7mΩ)在10 N下获得。电阻率在470和1700μΩ·cm之间变化,具体取决于孔隙率和O含量。

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